Crystal structure of [1,2-bis(diphenylphosphanyl)benzene]heptacarbonyldi-μ-hydrido-(μ3-2,4,6-trimethylphenylphosphinidene)-triangulo-triruthenium
نویسنده
چکیده
The title trinuclear ruthenium cluster, [Ru3(C30H24P2)(C9H11P)(CO)7(μ-H)2], has a triangular Ru3 core that is capped with a mesitylphosphin-idene ligand, μ3-PMes (Mes = mesityl = 2,4,6-tri-methyl-phen-yl). The 1,2-bis-(di-phenyl-phosphan-yl)benzene mol-ecule acts as a bidentate phosphine ligand via two P atoms connecting to a single Ru atom. The title compound crystallizes with two independent mol-ecules in the asymmetric unit.
منابع مشابه
Bis([μ-bis(diphenylarsino)methane-1:2κ2 As:As’]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-{tris[4-(methylsulfanyl)phenyl]arsine-3κAs}-triangulo-triruthenium(0)) dichloromethane monosolvate
The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)As(2))(C(21)H(21)AsS(3))(CO)(9)]·CH(2)Cl(2), consists of one triangulo-triruthenium complex mol-ecule and one half of a dichloro-methane mol-ecule which lies across a crystallographic inversion center, leading to the disorder of this mol-ecule over two positions of equal occupancy. The bis-(diphenyl-arsino)metha...
متن کاملBis{[μ-bis(diphenylphosphino)methane-1:2κ2 P:P′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[tris(4-methoxyphenyl)arsine-3κAs]-triangulo-triruthenium(0)} dichloromethane solvate
The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(21)H(21)AsO(3))(C(25)H(22)P(2))(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex mol-ecule and one half-mol-ecule of the dichloro-methane solvent. The dichloro-methane solvent lies across a crystallographic inversion center leading to the mol-ecule being disordered over two positions of equal occupancy. T...
متن کاملBis{[μ-bis(diphenylarsino)methane-1:2κ2 As:As′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[tris(4-methoxyphenyl)arsine-3κAs]-triangulo-triruthenium(0)} dichloromethane solvate
The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)As(2))(C(21)H(21)AsO(3))(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex mol-ecule and one half of the dichloro-methane solvent. The dichloro-methane solvent lies across a crystallographic inversion center leading to the mol-ecule being disordered over two positions of equal occupancy. The bis-(d...
متن کاملBis{[μ-bis(diphenylarsino)methane-1:2κ2 As:As′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[tris(4-chlorophenyl)phosphine-3κP]-triangulo-triruthenium(0)} chloroform monosolvate
The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)As(2))(C(18)H(12)Cl(3)P)(CO)(9)]·CHCl(3), consists of two mol-ecules (A and B) of the triangulo-triruthenium complex and one mol-ecule of chloro-form solvent. The bis-(diphenyl-arsino)methane ligand bridges an Ru-Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsi...
متن کامل[μ-Bis(diphenylphosphanyl)ethane-1:2κ2 P:P′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate
The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)AsO(3))(C(26)H(24)P(2))(CO)(9)]·CHCl(3), consists of one mol-ecule of the triangulo-triruthenium complex and one chloro-form solvent mol-ecule. The bis(diphenyl-phosphan-yl)ethane ligand bridges an Ru-Ru bond and the monodentate arsane ligand bonds to the third Ru atom. Both the arsane and phosphine ligands are e...
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عنوان ژورنال:
دوره 73 شماره
صفحات -
تاریخ انتشار 2017